JEE Main · ChemistryMedium

What is the product of the reaction between and concentrated ?

  1. A.
  2. B.
  3. C.
  4. D.
Show correct answer & step-by-step solution

Correct answer: A

Solution

  1. Benzaldehyde has no alpha-hydrogens, so it cannot undergo aldol condensation.
  2. In the presence of concentrated , it undergoes a disproportionation reaction known as the Cannizzaro reaction.
  3. One molecule of benzaldehyde is oxidized to sodium benzoate.
  4. Another molecule of benzaldehyde is reduced to benzyl alcohol.
  5. Hence the answer is (A).

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