JEE Main · ChemistryHard

The complex exhibits isomerism. How many total stereoisomers exist for this complex?

  1. A.2
  2. B.3
  3. C.4
  4. D.5
Show correct answer & step-by-step solution

Correct answer: B3

Solution

  1. The complex is of the type where A is a bidentate ligand.
  2. The trans isomer is achiral and has a plane of symmetry.
  3. The cis isomer is chiral and exists as a pair of optical enantiomers (d and l forms).
  4. Total stereoisomers = 1 (trans) + 2 (cis enantiomers) = 3.
  5. Hence the answer is (B).

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