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Potassium dichromate reacts with acidified hydrogen peroxide to form a deep blue colored compound. The oxidation state of chromium in this compound is:

  1. A.
  2. B.
  3. C.
  4. D.
Show correct answer & step-by-step solution

Correct answer: B

Solution

  1. The reaction of with in acidic medium produces .
  2. The structure of is a butterfly structure containing four peroxo linkages.
  3. In , the oxidation state of is calculated as is incorrect due to peroxo bonds.
  4. Assigning to each of the four peroxo oxygen atoms and to the double-bonded oxygen, we get , so .
  5. Hence the answer is (B).

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