JEE Main · ChemistryMedium

Which of the following is the correct order of stability for the given free radicals?

  1. A.
  2. B.
  3. C.
  4. D.
Show correct answer & step-by-step solution

Correct answer: B

Solution

  1. Free radicals are electron-deficient species stabilized by hyperconjugation and inductive effects.
  2. A tertiary radical has nine alpha-hydrogens available for hyperconjugation.
  3. A secondary radical has six alpha-hydrogens, and a primary radical has only three.
  4. Greater hyperconjugation leads to increased stability of the radical center.
  5. Hence the answer is (B).

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