JEE Main · ChemistryHard

Which of the following statements regarding the glass transition temperature () of polymers is correct?

  1. A.Tg is the temperature at which the polymer chains begin to undergo crystalline melting.
  2. B.Tg is independent of the molecular weight of the polymer.
  3. C.Tg is the temperature at which the amorphous regions of the polymer transition from a glassy state to a rubbery state.
  4. D.Tg is always higher than the melting temperature (Tm) of the polymer.
Show correct answer & step-by-step solution

Correct answer: CTg is the temperature at which the amorphous regions of the polymer transition from a glassy state to a rubbery state.

Solution

  1. Below , the polymer chains are frozen in a glassy, rigid state.
  2. At , the amorphous regions gain enough thermal energy for long-range segmental motion.
  3. This transition is distinct from crystalline melting, which involves the breakdown of ordered lattice structures.
  4. The is generally lower than the melting temperature .
  5. Hence the answer is (C).

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