JEE Main · ChemistryMedium

Which of the following statements regarding the structure and properties of is correct?

  1. A.It exists in two anomeric forms, and , which differ in configuration at .
  2. B.It reacts with to form a cyclic oxime.
  3. C.The open chain form contains a free aldehyde group that reacts with reagent.
  4. D.It forms a stable hemiacetal with in the presence of acid.
Show correct answer & step-by-step solution

Correct answer: AIt exists in two anomeric forms, and , which differ in configuration at .

Solution

  1. exists in equilibrium between its open-chain and cyclic hemiacetal forms.
  2. The cyclic forms are and .
  3. These two forms differ only in the configuration at the anomeric carbon, .
  4. Hence the answer is (A).

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