JEE Main · ChemistryMedium

Which of the following compounds will show the highest reactivity towards electrophilic aromatic substitution?

  1. A.
  2. B.
  3. C.
  4. D.
Show correct answer & step-by-step solution

Correct answer: C

Solution

  1. Electrophilic aromatic substitution reactivity depends on the electron density of the benzene ring.
  2. Electron-donating groups increase electron density, while electron-withdrawing groups decrease it.
  3. The methyl group in toluene is an activating group due to the effect and hyperconjugation.
  4. Nitrobenzene is strongly deactivated, while chlorobenzene is weakly deactivated.
  5. Hence the answer is (C).

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